LIBS Info: Element Analysis
| Title | Authors | Material | Detector | Spectrometer | Software |
|---|---|---|---|---|---|
| Comparison of the Detection Characteristics of Trace Species Using Laser-Induced Breakdown Spectroscopy and Laser Breakdown Time-of-Flight Mass Spectrometry | Jiping Liu, Yoshihiro Deguchi, Junjie Yan, ZhenZhen Wang | Gases | ICCD | Czerny-Turner (Unspecified) | |
| Laser: | Nd:YAG 1064.0000nm 400.0000mJ 10.000Hz |
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| Gate Delay: | 1.060us | ||||
| Gate Width: | 30.000us | ||||
| LIBS is applied to the detection of Hg and I in gases at low pressure in air and pure N2 using nanosecond and 35ps pulse length lasers. The authors experimented with different gas pressures, with low pressure providing the best detection limits. The effect of laser power and gate delay were also investigated. | |||||
| Element | Detection Limit (ppm) | Wavelength (nm) | Other Wavelengths (nm) | Calibration Method | Calibration Range (ppm) | Notes |
|---|---|---|---|---|---|---|
| I | 0.2100 (Calibration Curve Slope) | 183.0000 | N/A | Univariate | -10.0000--10.0000 | Detection limit in gas samples, using low pressure Nitrogen as the buffer gas. 35 picosecond laser pulses. |
| I | 0.0600 (Calibration Curve Slope) | 183.0000 | N/A | Univariate | -10.0000--10.0000 | Detection limit in gas samples, using low pressure Nitrogen as the buffer gas. Nanosecond laser pulses. |
| I | 3.4400 (Calibration Curve Slope) | 183.0000 | N/A | Univariate | -10.0000--10.0000 | Detection limit in gas samples, using low pressure air as the buffer gas. 35 picosecond laser pulses. |
| I | 2.6600 (Calibration Curve Slope) | 183.0000 | N/A | Univariate | -10.0000--10.0000 | Detection limit in gas samples, using low pressure air as the buffer gas. Nanosecond laser pulses. |
| Hg | 0.0300 (Calibration Curve Slope) | 253.7000 | N/A | Univariate | 0.3000-1.5000 | Detection limit in gas samples, using low pressure air as the buffer gas. 35 picosecond laser pulses. |
| Hg | 0.0035 (Calibration Curve Slope) | 253.7000 | N/A | Univariate | 0.3000-1.5000 | Detection limit in gas samples, using low pressure Nitrogen as the buffer gas. Nanosecond laser pulses. |
| Hg | 0.4500 (Calibration Curve Slope) | 253.7000 | N/A | Univariate | 0.3000-1.5000 | Detection limit in gas samples, using low pressure air as the buffer gas. Nanosecond laser pulses. |
| Element | RMSE (ppm) | Wavelength (nm) | Calibration Method | Notes |
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