LIBS Info: Element Analysis
Title | Authors | Material | Detector | Spectrometer | Software |
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Calibration-free laser induced breakdown spectroscopy as an alternative method for found meteorite fragments analysis | Vladimir Porubcan, P. Veis, Daniel Ozdin, Jozef Rakovsky, Jozef Plavcan, Michaela Hornackova | Geological | Andor iStar ICCD | Mechelle 5000 | LabView |
Laser: | Nd:YAG 532.0000nm 165.0000mJ 10.000Hz |
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Gate Delay: | 2.500us | ||||
Gate Width: | 0.500us | ||||
The authors use CF-LIBS to analyse 3 fragments of the Kosice Meteorite. Results are compared to ICP-OES. Electron density was determined from the H(alpha) line width. Lines with high probability of self-absorption were removed from the analysis where possible, however in the case of Na and Al this was not possible, leading to larger uncertainties in the results. |
Element | Detection Limit (ppm) | Wavelength (nm) | Other Wavelengths (nm) | Calibration Method | Calibration Range (ppm) | Notes |
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Element | RMSE (ppm) | Wavelength (nm) | Calibration Method | Notes |
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Ni | 300.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |
Fe | 11400.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |
Mn | 50.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results. [Estimate of uncertainty based on significant figures] |
Cr | 800.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |
Ca | 800.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |
Si | 4500.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |
Al | 8100.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |
Mg | 7000.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |
Na | 11900.0000 ppm | -10.0000 | CF-LIBS | Average CF-LIBS result compared to ICP-MS results |