LIBS Info: Element Analysis

Title	Authors	Material	Detector	Spectrometer	Software
Ultrafast laser induced breakdown spectroscopy for high spatial resolution chemical analysis	Vassilia Zorba, Xianglei Mao, Richard E. Russo	Geological	Jobin Yvon ICCD i3000	Jobin-Yvon HRP
Laser:	Ti:Sapphire 400.0000nm NonemJ 1.000Hz
Gate Delay:	Noneus
Gate Width:	Noneus
The key point of this paper is to explore the limits of very high resolution spatial analysis of samples. This is achieved using 100fs pulses and a very small focal spot. Craters of 450nm where achieved while still detecting Na and K in a Mica sample. Detection limits as low as 220 10^-18g (6 10^6 atoms) for Na and 4.2 10^-15 g (3.2 10^7 atoms) for K were achieved.

LOD
RMSEP

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Element	Detection Limit (ppm)	Wavelength (nm)	Other Wavelengths (nm)	Calibration Method	Calibration Range (ppm)	Notes
Na	2700.0000 (Calibration Curve Slope)	588.9900	589.59	Univariate	-10.0000--10.0000	This detection limit corresponds to 102 10^-18g of sample due to the very small (1um) laser spot size

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Element	RMSE (ppm)	Wavelength (nm)	Calibration Method	Notes
No data available in table

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