LIBS Info: Element Analysis
Title | Authors | Material | Detector | Spectrometer | Software |
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Ultrafast laser induced breakdown spectroscopy for high spatial resolution chemical analysis | Vassilia Zorba, Xianglei Mao, Richard E. Russo | Geological | Jobin Yvon ICCD i3000 | Jobin-Yvon HRP | |
Laser: | Ti:Sapphire 400.0000nm NonemJ 1.000Hz |
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Gate Delay: | Noneus | ||||
Gate Width: | Noneus | ||||
The key point of this paper is to explore the limits of very high resolution spatial analysis of samples. This is achieved using 100fs pulses and a very small focal spot. Craters of 450nm where achieved while still detecting Na and K in a Mica sample. Detection limits as low as 220 10^-18g (6 10^6 atoms) for Na and 4.2 10^-15 g (3.2 10^7 atoms) for K were achieved. |
Element | Detection Limit (ppm) | Wavelength (nm) | Other Wavelengths (nm) | Calibration Method | Calibration Range (ppm) | Notes |
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Na | 2700.0000 (Calibration Curve Slope) | 588.9900 | 589.59 | Univariate | -10.0000--10.0000 | This detection limit corresponds to 102 10^-18g of sample due to the very small (1um) laser spot size |
Element | RMSE (ppm) | Wavelength (nm) | Calibration Method | Notes |
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