LIBS Info: Element Analysis
Title | Authors | Material | Detector | Spectrometer | Software |
---|---|---|---|---|---|
Laser Ablation Molecular Isotopic Spectrometry | Richard E. Russo, Alexander A. Bol'shakov, Xianglei Mao, Christopher P. McKay, Dale L. Perry, Osman Sorkhabi | Isotopes | ICCD | Czerny-Turner (Unspecified) | |
Laser: | Nd:YAG 1064.0000nm 50.0000mJ NoneHz |
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Gate Delay: | 25.000us | ||||
Gate Width: | 60.000us | ||||
In this paper, a LIBS method is used to measure the isotope concentrations in samples. The method uses the shifts in vibrational/rotational peaks caused by the different isotope mass [which can be significantly larger than the atomic emission change due to the isotope mass]. Hydrogen, Boron, Carbon and Oxygen isotopes are discussed |
Element | Detection Limit (ppm) | Wavelength (nm) | Other Wavelengths (nm) | Calibration Method | Calibration Range (ppm) | Notes |
---|---|---|---|---|---|---|
B | 10000.0000 (Minimum Concentration Detected) | -10.0000 | N/A | LAMIS (with PLS) | -10.0000--10.0000 | Estimated from LAMIS results for determination of Boron(10) in Boron Nitride. |
Element | RMSE (ppm) | Wavelength (nm) | Calibration Method | Notes |
---|---|---|---|---|
B | 0.4000 % | -10.0000 | LAMIS | Determination of Boron(10) as a fraction of a sample containing both Boron(10) and Boron(11) |